Just about anything is possible using excel. Depending on what sort of correlation you're looking for you could have a third column to display whether both stocks moved up or down together on a given day. eg..
=IF(OR(AND(A2-A1>0,B2-B1>0),AND(A2-A1<0,B2-B1<0)),1,"")
That will display a 1 in the third column if both stocks went up or down together. Then you can add up the 1's and get a % of the total days that the stocks moved up or down together.
or something like that anyway